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한국전기화학회 한국전기화학회

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Vol.16, No.4, November 2013

Determination of the Frumkin and Temkin Adsorption Isotherms of Underpotentially Deposited Hydrogen at Pt Group Metal Interfaces Using the Standard Gibbs Energy of Adsorption and Correlation Constants
JKES Vol.16, No.4, pp.211-216, November 2013
DOI : 10.5229/JKES.2013.16.4.211
Jinyoung Chun1, Sang K. Jeon2, and Jang H. Chun*,3
1Department of Chemical Engineering, Pohang University of Science and Technology, Pohang, Kyungbuk 790-784, Republic of Korea 2International Cooperation Division, Korea Institute of Lighting Technology, Bucheon, Kyunggi 420-806, Republic of Korea 3Department of Electronic Engineering, Kwangwoon University, Seoul 139-701, Republic of Korea
At Pt(111), Pt(100), Pt, and Rh interfaces, the Frumkin adsorption isotherm of underpotentially deposited hydrogen (UPD H) and related electrode kinetic data are determined using the standard Gibbs energy of adsorption. The Temkin adsorption isotherm of UPD H correlating with the Frumkin adsorption isotherm of UPD H is readily determined using the correlation constants between the Temkin and Frumkin or Langmuir adsorption isotherms. At the Pt(111), Pt(100), Pt, and Rh interfaces, the lateral repulsive interaction between the UPD H species is interpreted using the interaction parameter for the Frumkin adsorption isotherm. The lateral repulsive interaction between the UPD H species at the Pt(111), Pt(100), Pt, and Rh interfaces is significantly different from the lateral attractive interaction between the overpotentially deposited hydrogen (OPD H) species at Pt, Ir, and Pt-Ir alloy interfaces.
Keyword : Underpotentially and overpotentially deposited hydrogen; Frumkin, Langmuir, and Temkin adsorption isotherms; Pt group metal electrodes; Standard Gibbs energy of adsorption; Correlation constants

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